Synthesis, Crystal Structure and Characterization of a New Dabcodiium Hexaaquacobalt(II) Bis(Selenate), (C6H14N2)[Co(H2O)6](SeO4)2

Abstract  

The new hybrid material, cobalt selenate templated by 1,4-diazabicyclo[2.2.2]octane (abbreviated dabco), has been synthesised by the slow evaporation method at room temperature. Its crystal structure was investigated using single crystal X-ray diffraction data. It crystallises in the monoclinic system (space group P2₁/c) with the following unit-cell parameters: a = 12.9169(2) ?, b = 11.9101(2) ?, c = 12.4951(2) ?, β = 108.484(1)°, V = 1823.10(5) ?³ and Z = 4. The supramolecular structure of (C₆H₁₄N₂)[Co(H₂O)₆](SeO₄)₂ consists of isolated [Co(H₂O)]²⁺ and (C₆H₁₄N₂)²⁺ cations and (SeO₄)²⁻ anions linked together by three dimensional hydrogen-bond network. The infrared spectroscopy confirmed the presence of these different entities. The thermal behaviour of the precursor, studied by thermodiffractometry and thermogravimetric analyses, indicates that its decomposition proceeds through three stages giving rise to the cobalt oxide.     

A conductometric biosensor for the estimation of the number of cleaving sites in peptides and proteins

A conductometric enzyme biosensor using proteinase K was developed and then tested to relate its electrical signal to the number of proteinase K hydrolysis sites in bovine serum albumin (BSA) and angiotensin, a ten amino acid peptide, with one cleaving site.The conductometric sensor presents a large linear range of response for BSA and angiotensin ranging from 0.5 to 8 mg/l and from 4 to 8 mg/l, respectively. For a same tested concentration (mg/l), the response for native BSA is 12 times higher than for angiotensin. Aspartam was used as negative test and no response was obtained with the proteinase K biosensor. The conductometric sensor permitted also to detect difference on enzyme activity on native and non-native BSA, a response three times higher was obtained for non-native BSA.     

Stabilité de l'écoulement de Hartmann chauffé par le basStability of the Hartmann flow heated from below

A numerical study is conducted in order to determine the influence of a vertical magnetic field, the Reynolds number and a temperature stratification on the instabilities occurring in the Hartmann flow heated from below. For $\mathit{Pr}=0.001$ and $\mathit{Ha}?2.5$, the results show that the vertical magnetic field has a stabilizing effect on both transverse oscillatory travelling waves $(T)$ and longitudinal stationary rolls $(L)$. The temperature stratification is responsible of a destabilization of the transverse $(T)$ modes and the appearance of longitudinal $(L)$ modes non-existent for the isothermal Hartmann flow. Moreover, the extent of the domains of Re where the transverse modes $(T)$ prevail is found to narrow when Ha increases and to widen when Ra increases for a given value of Ha. On the other hand, for the $(L)$ modes, the extent of the domains of Re where they prevail increases when Ha grows. To cite this article: W. Fakhfakh et al., C. R. Mecanique 334 (2006).     

Computational methods for delay parabolic and time‐fractional partial differential equations

This article is concerned with ?‐methods for delay parabolic partial differential equations. The methodology is extended to time‐fractional‐order parabolic partial differential equations in the sense of Caputo. The fully implicit scheme preserves delay‐independent asymptotic stability and the solution continuously depends on the time‐fractional order. Several numerical examples of interest are included to demonstrate the effectiveness of the method. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2010     

A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition

The crystal structure of manganese sulfate templated by 1,4-diaza-bicyclo[2.2.2]octane (abbreviated dabco), (C₆H₁₄N₂)[Mn(H₂O)₆](SO₄)₂, was investigated using single crystal X-ray diffraction data. It crystallises in the monoclinic system (space group P2₁/c) with the following unit-cell parameters: a = 12.1392(2) ?, b = 12.3117(2) ?, c = 12.2765(2) ?, β = 104.607(1)°, V = 1775.47(5) ?³ and Z = 4. The structure has been solved using direct methods and refined by least-squares analysis [R ₁ = 0.0381, wR ₂ = 0.1082]. The crystal structure of the title compound is built from isolated [Mn(H₂O)₆]²⁺ octahedral cations, 1,4-diaza-bicyclo[2.2.2]octandiium cations (C₆H₁₄N₂)²⁺ and sulfate anions (SO₄)²⁻ connected by a three-dimensional hydrogen-bond network. The thermal decomposition of the precursor, studied by thermogravimetry and temperature-dependent X-ray powder diffraction, proceeds through four stages giving rise to the mixture of Mn₂O₃and Mn₃O₄. Supplementary Material CCDC 620298 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.     

Cyclic Thermodynamic Processes and Entropy Production

We study the time evolution of a periodically driven quantum-mechanical system coupled to several reservoirs of free fermions at different temperatures. This is a paradigm of a cyclic thermodynamic process. We introduce the notion of a Floquet Liouvillean as the generator of the dynamics of the coupled system on an extended Hilbert space. We show that the time-periodic state which the state of the coupled system converges to after very many periods corresponds to a zero-energy resonance of the Floquet Liouvillean. We then show that the entropy production per cycle is (strictly) positive, a property that implies Carnot's formulation of the second law of thermodynamics.     

Synthesis and characterization of hydrophobic silica nanocomposites

Hydrophobically modified silica nanocomposites have been prepared using a low temperature sol-gel process. In this study, an alkyltriethoxysilane derivative, hexdecyltrimethoxysilane (HDTMS), was co-condensed with tetraethoxyorthosilicate (TEOS) with and without a cross-linking agent, 3-glycidoxypropyltrimethoxysilane (GPTMS), to produce the modified composites. The hydrophobic properties were determined using contact angle measurement. FESEM observations revealed a semispherical nanostructure of the composites with grain size of about 50-75 nm in diameter. The chemical modification was studied by FTIR and EDX, whereas the physicothermal properties were analyzed by DSC and TGA. These long-chain alkyl modified silica nanocomposites are promising materials for use in hydrophobic and water-resistant applications.     

N1‐allyl‐3‐substituted‐6,7‐dimethyl‐1,2‐dihydro‐2‐quinoxalinone as key intermediate for new acyclonucleosides and their regioisomer O‐analogues

The key intermediates allyloxyquinoxaline 2a–c and N‐allylquinoxaline 3a–c were used to synthesize a number of acyclonucleosides whose chemical modifications include quinoxaline ring and the acyclic part is either N¹‐propanediol or 3‐hydroxy‐ propyl substituents and their O‐analogues. These compounds were characterized by elemental analysis, MALDI MS, and NMR data. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:280–288, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20203     

Dielectric Properties of Polyimide‐Mica Hybrid Films

Summary: Polyimide‐mica hybrid films were prepared via ultrasonic dispersion and in situ polymerization process from a solution of a polyimide precursor and mica in N,N‐dimethylacetamide, and their structure was characterized by FTIR and XRD techniques. The dependence of dielectric properties, such as dielectric constant and electrical breakdown strength, of the hybrid films on the content of mica was studied at room and cryogenic temperatures. The results show that the dielectric constant of PI‐mica hybrid films decreases with the increase of the mica content at temperatures from −150 to 150 °C and at frequency range from 1 kHz to 1 MHz. It was found that the cryogenic electrical breakdown strength of the PI‐mica hybrid films could meet the requirements of cryogenic insulating materials.

Effect of frequency on the dielectric constant of PI‐mica hybrid films at 140 °C at the frequency from 1 kHz to 1 MHz.     

Mastery of Cultural Conditions and Physico-chemical Properties Improves the Production and the Catalytic Efficiency of bglG

Stachybotrys microspora is a filamentous fungus secreting multiple β-glucosidases. Two of them were characterized. The third one, named bglG, was also characterized and used for various investigations. The current work undertakes the plausible role played by some cultural conditions and physico-chemical properties to improve bglG time course synthesis and also its catalytic efficiency. Indeed, bglG time course synthesis is slightly affected by light, but it is clearly affected by aeration and presence of baffle. On the same case, optimization of substrate and enzyme concentration contributes to the improvement of the catalytic efficiency of bglG. This biocatalyst tolerates a high ionic strength during its activity assay; β-mercaptoethanol increases the enzymatic rate. BglG has the capacity to hydrolyse efficiently oleuropéin, with a recovery of 88 %.